Source:http://linkedlifedata.com/resource/pubmed/id/18333610
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
7
|
| pubmed:dateCreated |
2008-4-1
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| pubmed:abstractText |
Complexes [{(mu-SCH2)2NCH2C6H5}{Fe(CO)2L(1)}{Fe(CO)2L(2)}] (L(1) = CO, L(2) = P(Pyr) 3, 2; L(1) = L(2) = P(Pyr)3, 3) were prepared, which have the lowest reduction potentials for the mono- and double-CO-displaced diiron complexes reported so far. Hydrogen evolution, driven by visible light, was successfully observed for a three-component system, consisting of a ruthenium polypyridine complex, the biomimetic model complex 2 or 3, and ascorbic acid as both electron and proton donor in CH3CN/H2O. The electron transfer from photogenerated Ru(bpy)3(+) to 2 or 3 was detected by laser flash photolysis. Under optimal conditions, the total turnover number for hydrogen evolution was 4.3 based on 2 and 86 based on Ru(bpy)3(2+) in a three-hour photolysis.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Apr
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| pubmed:issn |
0020-1669
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| pubmed:author | |
| pubmed:issnType |
Print
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| pubmed:day |
7
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| pubmed:volume |
47
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
2805-10
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| pubmed:year |
2008
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| pubmed:articleTitle |
Visible light-driven electron transfer and hydrogen generation catalyzed by bioinspired [2Fe2S] complexes.
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| pubmed:affiliation |
State Key Laboratory of Fine Chemicals, DUT-KTH Joint Education and Research Centre on Molecular Devices, Dalian University of Technology, 116012 Dalian, China.
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| pubmed:publicationType |
Journal Article
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