Source:http://linkedlifedata.com/resource/pubmed/id/18322630
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
11
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| pubmed:dateCreated |
2008-3-6
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| pubmed:abstractText |
A series of mono-, di- and trimeric oxo-centred triruthenium cluster compounds with ortho-metallated polypyridyl ligands were prepared by reaction of oxo-centred triruthenium precursor compound [Ru3O(OAc)6(py)2(CH3OH)]+ (1) with bis(2,2'-bipyridin-5-yl)butadiyne (bpyC[triple bond, length as m-dash]C-C[triple bond, length as m-dash]Cbpy), bis(2,2'-bipridin-5-yl)ethyne (bpyC[triple bond, length as m-dash]Cbpy), 2,2'-bipyrazine (bpz), pyrazino[2,3-f]quinoxaline (pyq), or 4,7-phenanthroline (4,7-phen). As revealed by redox wave splitting, electronic interactions are operating between two Ru3O redox centres in most of the triruthenium cluster dimers and trimers. The cluster-cluster interactions are highly sensitive to the variations in bonding modes of the polypyridyl ligands. Ortho-metallation of the bridging ligand induces an enhanced electronic interaction between two triruthenium centres.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Mar
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| pubmed:issn |
1477-9226
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| pubmed:author | |
| pubmed:issnType |
Print
|
| pubmed:day |
21
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| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
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| pubmed:pagination |
1492-502
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| pubmed:year |
2008
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| pubmed:articleTitle |
Syntheses, characterization and redox properties of oxo-centred triruthenium cluster dimers and trimers linked by ortho-metallated polypyridyl ligands.
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| pubmed:affiliation |
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China.
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| pubmed:publicationType |
Journal Article
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