Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
22
pubmed:dateCreated
2007-12-13
pubmed:abstractText
Zeolite matrix FAU is applied as an effective support that can be readily exchanged with ferric ions simply by wet ion exchange. The high exchange degree in this zeolite (USY) probably benefits from its larger channel dimension, which makes the diffusion of hydrated ferric ions into the channels easier. The as-prepared and subsequently calcined Fe-USY samples contain various kinds of iron species, which enable Fe-USY to efficiently decompose N2O to N2 and O2. The presence of O2 (20%), H2O (2%), or both reduces the N2O conversion only to a small extent at the same temperature. To test the feasibility and the catalytic activity in a practical situation, we prepared a monolithic Fe-USY/cordierite sample and investigated the N2O conversion under similar conditions. Such a cordierite-supported Fe-USY catalyst (approximately 9 wt % USY and 0.5 wt % Fe) shows the catalytic performance in N20 decomposition similar to the pure Fe-USY catalyst. Remarkably, both the pure Fe-USY and Fe-USY/cordierite catalysts demonstrate a very good durability because there is no activity lost after 100 and 144 h tests. Thus, the Fe-USY zeolite shows its potential as a cost-effective catalyst for N2O elimination in future applications.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Nov
pubmed:issn
0013-936X
pubmed:author
pubmed:issnType
Print
pubmed:day
15
pubmed:volume
41
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
7901-6
pubmed:meshHeading
pubmed:year
2007
pubmed:articleTitle
Fe-USY zeolite catalyst for effective decomposition of nitrous oxide.
pubmed:affiliation
Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, PR China.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't