Source:http://linkedlifedata.com/resource/pubmed/id/18052054
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
26
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| pubmed:dateCreated |
2007-12-17
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| pubmed:abstractText |
A novel zero-dimensional (0D) octacyanotungstate(V)-manganese(II) bimetallic assembly, {[MnII(bipy)2]2(ox)}.{[MnII(bipy)2W(CN)8]2}.4H2O (1) (bipy = 2,2'-bipyridine, ox = C2O42-), was synthesized in methanol solution containing oxalic acid. X-ray analysis shows 1 is crystallized in monoclinic crystal system with C2/c space group and composed of two components of a dimeric Mn2 cation and a quadrate tetrameric Mn2W2 anion. The Mn2 and Mn2W2 moieties are connected by their respective pi-pi stacking to yield the alternative 2D layers, and the 2D layers are linked by hydrogen bonding to form a 3D network. The investigation of the magnetostructural correlation reveals that cyanide and oxalate bridges mediate weak intracluster antiferromagnetic coupling between Mn and W ions and between Mn ions, respectively. Further magnetic measurements and analysis show the spin glasses and intercluster ferromagnetic interaction exist in complex 1.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Dec
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| pubmed:issn |
0020-1669
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| pubmed:author | |
| pubmed:issnType |
Print
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| pubmed:day |
24
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| pubmed:volume |
46
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| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
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| pubmed:pagination |
10990-5
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| pubmed:year |
2007
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| pubmed:articleTitle |
Octacyanotungstate(V)-based magnetic complex consisting of dimeric Mn(2) and tetrameric Mn(2)W(2).
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| pubmed:affiliation |
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, China.
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| pubmed:publicationType |
Journal Article
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