Linked Life Data

17902906

Source:http://linkedlifedata.com/resource/pubmed/id/17902906

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
12
pubmed:dateCreated
2007-10-1
pubmed:abstractText
The beta angular asymmetry and D dichroic asymmetry parameters of the methyl-oxirane highest occupied molecular orbital (HOMO) band have been experimentally investigated with vibrational resolution using synchrotron radiation. A theoretical calculation of the Franck-Condon factors between vibrational ground state and different ionic vibrational states, in the Born-Oppenheimer harmonic approximation, has been performed in order to gain information on the vibrational states mainly involved in the HOMO photoelectron band. The general good agreement between theoretical and experimental results allows a reliable assignment of the major features. The experimental determination of beta and D shows their dependence on the different final vibrational states. This paper reports, for the first time, experimental evidence of the dependence of the dichroic D parameter on the vibrational excitation of the ion.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Sep
pubmed:issn
0021-9606
pubmed:author
pubmed:issnType
Print
pubmed:day
28
pubmed:volume
127
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
124310
pubmed:year
2007
pubmed:articleTitle
Vibrational state dependence of beta and D asymmetry parameters: the case of the highest occupied molecular orbital photoelectron spectrum of methyl-oxirane.
pubmed:affiliation
CNR-ISM, Area della Ricerca di Tor Vergata, Via Del Fosso del Cavaliere 100, I-00133 Roma, Italy. Giorgio.Contini@ism.cnr.it
pubmed:publicationType
Journal Article