Linked Life Data

17303750

Source:http://linkedlifedata.com/resource/pubmed/id/17303750

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
5814
pubmed:dateCreated
2007-2-16
pubmed:abstractText
We report a synthetic material, [Co2(bipy)3(SO4)2(H2O)2](bipy) (CH3OH), (1, where bipy = 4,4'-bipyridyl) that contains discrete reactive and inert structural motifs that undergo a reversible substitution reaction involving the concerted and spatially controlled introduction of bipyridine and methanol molecules at the reactive sites. This reaction defines the pore geometry of the resulting open-framework structure and controls the manner in which this structure sorbs small molecules. The molecules involved in the reaction are positioned by an array of well-defined interactions during their path to binding to the metal centers.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Feb
pubmed:issn
1095-9203
pubmed:author
pubmed:issnType
Electronic
pubmed:day
16
pubmed:volume
315
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
977-80
pubmed:year
2007
pubmed:articleTitle
Reversible concerted ligand substitution at alternating metal sites in an extended solid.
pubmed:affiliation
Department of Chemistry, University of Liverpool, Liverpool L69 7ZD, UK.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't