Source:http://linkedlifedata.com/resource/pubmed/id/17291447
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
6
|
| pubmed:dateCreated |
2007-6-8
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| pubmed:abstractText |
The synthesis and electrochemistry of half-sandwich type of Co(III) complexes [(C(5)Me(5))Co(bidentate)(CH(3)CN)](BF(4))(2) {bidentate=dppe (1,2-bis(diphenylphosphino)ethane), dppp (1,3-bis(diphenylphosphino)propane), bpy (2,2'-bipyridine), en (ethylenediamine)) are reported. Cyclic voltammograms of [(C(5)Me(5))Co(bidentate)(CH(3)CN)](BF(4))(2) in CH(3)CN s showed two redox couples assignable to Co(II)/Co(III) and Co(I)/Co(II). The Co(I) complex having C(5)Me(5) and dppe was also prepared. Two redox couples of this Co(I) complex, (C(5)Me(5))Co(dppe), in CH(3)CN coincided with those of [(C(5)Me(5))Co(dppe)(CH(3)CN)](BF(4))(2) in spite of the structural change around the metal center.
|
| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:citationSubset |
IM
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| pubmed:chemical | |
| pubmed:status |
MEDLINE
|
| pubmed:month |
Jun
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| pubmed:issn |
0006-3002
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| pubmed:author | |
| pubmed:issnType |
Print
|
| pubmed:volume |
1767
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| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
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| pubmed:pagination |
666-70
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| pubmed:meshHeading |
pubmed-meshheading:17291447-Cobalt,
pubmed-meshheading:17291447-Electrochemistry,
pubmed-meshheading:17291447-Models, Chemical,
pubmed-meshheading:17291447-Molecular Structure,
pubmed-meshheading:17291447-Organometallic Compounds,
pubmed-meshheading:17291447-Oxidation-Reduction,
pubmed-meshheading:17291447-Structure-Activity Relationship
|
| pubmed:year |
2007
|
| pubmed:articleTitle |
Synthesis and electrochemistry of Co(III) and Co(I) complexes having C5Me5 auxiliary.
|
| pubmed:affiliation |
Research Center for Molecular-scale Nanoscience, Institute for Molecular Science, Myodaiji, Okazaki 444-8787, Japan. tnaga@ims.ac.jp
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| pubmed:publicationType |
Journal Article
|