Linked Life Data

17198430

Source:http://linkedlifedata.com/resource/pubmed/id/17198430

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PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
1
pubmed:dateCreated
2007-1-2
pubmed:abstractText
The mixed-anion coordination polymer Cu(HCO2)(NO3)(pyz) was synthesized, its crystal structure was determined by X-ray diffraction, and its magnetic structure was characterized by ac susceptibility, dc magnetization, muon-spin relaxation, and spin dimer analysis. The crystal structure consists of five-coordinate Cu2+ ions that are connected through syn-anti bridging mu-HCO2- and mu-pyz ligands to form a highly corrugated two-dimensional layered network. Bulk magnetic measurements show a broad maximum in chi(T) at 6.6 K. The HCO2- and pyz ligands mediate ferromagnetic and antiferromagnetic spin exchange interactions between adjacent Cu2+ ions with the spin exchange parameters J/kB = 8.17 and -5.4 K, respectively (H = -JSigmaSi x Sj). The muon-spin relaxation data show a transition to a long-range magnetic ordering below TN = 3.66(3) K. For T < TN, the M(H) and chi'ac measurements provide evidence for a field-induced spin-flop transition at 15.2 kOe. That Cu(HCO2)(NO3)(pyz) undergoes a long-range magnetic ordering is an unexpected result because the one-dimensional Cu(NO3)2(pyz) and three-dimensional Cu(HCO2)2(pyz) compounds display linear chain antiferromagnetism with no long-range magnetic ordering down to 2 K.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Jan
pubmed:issn
0020-1669
pubmed:author
pubmed:issnType
Print
pubmed:day
8
pubmed:volume
46
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
213-20
pubmed:year
2007
pubmed:articleTitle
Characterization of the crystal and magnetic structures of the mixed-anion coordination polymer Cu(HCO2)(NO3)(pyz) {pyz = Pyrazine} by X-ray diffraction, ac magnetic susceptibility, dc magnetization, muon-spin relaxation, and spin dimer analysis.
pubmed:affiliation
Condensed Matter Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA. jmanson@ ewu.edu
pubmed:publicationType
Journal Article