Source:http://linkedlifedata.com/resource/pubmed/id/17018260
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
3-4
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pubmed:dateCreated |
2007-5-29
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pubmed:abstractText |
In this paper, the spectroscopic properties of Nd(3+) doped transparent oxyfluoride glass ceramics containing LaF(3) nano-crystals were systematically studied. The formation and distribution of LaF(3) nano-crystals in the glass matrix were investigated by X-ray diffraction (XRD) and transmission electron microscopy (TEM). Based on Judd-Ofelt theory, the intensity parameters Omega(t) (t=2, 4, 6), spontaneous emission probability, radiative lifetime, radiative quantum efficiency, width of the emission line and stimulated emission cross-section of Nd(3+) were evaluated. Particularly, the effect of Nd(3+) doping level on them was discussed. With the increase of Nd(3+) concentration in the glass ceramic, the experimental luminescence lifetime, radiative quantum efficiency and stimulated emission cross-section vary from 353.4 micros, 78.3% and 1.86 x 10(-20)cm(2) to 214.7 micros, 39.9% and 1.52 x 10(-20)cm(2), respectively. The comparative study of Nd(3+) spectroscopic parameters in different hosts suggests that the investigated glass ceramic system is potentially applicable as laser materials for 1.06 microm emission.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical |
http://linkedlifedata.com/resource/pubmed/chemical/Ceramics,
http://linkedlifedata.com/resource/pubmed/chemical/Fluorine,
http://linkedlifedata.com/resource/pubmed/chemical/Ions,
http://linkedlifedata.com/resource/pubmed/chemical/Neodymium,
http://linkedlifedata.com/resource/pubmed/chemical/Oxides,
http://linkedlifedata.com/resource/pubmed/chemical/fluorine monoxide
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pubmed:status |
MEDLINE
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pubmed:month |
Jul
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pubmed:issn |
1386-1425
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:volume |
67
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
709-13
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pubmed:meshHeading |
pubmed-meshheading:17018260-Ceramics,
pubmed-meshheading:17018260-Fluorine,
pubmed-meshheading:17018260-Glass,
pubmed-meshheading:17018260-Ions,
pubmed-meshheading:17018260-Microscopy, Electron, Transmission,
pubmed-meshheading:17018260-Nanoparticles,
pubmed-meshheading:17018260-Neodymium,
pubmed-meshheading:17018260-Oxides,
pubmed-meshheading:17018260-Particle Size,
pubmed-meshheading:17018260-Spectrophotometry,
pubmed-meshheading:17018260-X-Ray Diffraction
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pubmed:year |
2007
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pubmed:articleTitle |
Spectroscopic properties of Nd3+ doped transparent oxyfluoride glass ceramics.
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pubmed:affiliation |
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Graduate School of Chinese Academy of Sciences, Fuzhou, Fujian 350002, China.
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pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
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