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pubmed-article:16827593pubmed:abstractTextWe have investigated the dispersion of single-walled carbon nanotubes (SWNTs) and functionalized SWNTs (F-SWNTs) in the unsaturated, biodegradable polymer poly(propylene fumarate) (PPF) and examined the rheological properties of un-cross-linked nanocomposite formulations as well as the electrical and mechanical properties of cross-linked nanocomposites. F-SWNTs were produced from individual SWNTs by a diazonium-based method and dispersed better than unmodified SWNTs in both un-cross-linked and cross-linked PPF matrix. Cross-linked nanocomposites with F-SWNTs were superior to those with unmodified SWNTs in terms of their mechanical properties. Specifically, nanocomposites with 0.1 wt % F-SWNTs loading resulted in a 3-fold increase in both compressive modulus and flexural modulus and a 2-fold increase in both compressive offset yield strength and flexural strength when compared to pure PPF networks, whereas the use of 0.1 wt % SWNTs gained less than 37% mechanical reinforcement. These extraordinary mechanical enhancements considered together with Raman scattering and sol fraction measurements indicate strong SWNT-PPF interactions and increased cross-linking densities resulting in effective load transfer. With enhanced mechanical properties and capabilities of in situ injection and cross-linking, these SWNT/polymer nanocomposites hold significant implications for the fabrication of bone tissue engineering scaffolds.lld:pubmed
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pubmed-article:16827593pubmed:pagination2237-42lld:pubmed
pubmed-article:16827593pubmed:dateRevised2007-11-14lld:pubmed
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pubmed-article:16827593pubmed:year2006lld:pubmed
pubmed-article:16827593pubmed:articleTitleInjectable nanocomposites of single-walled carbon nanotubes and biodegradable polymers for bone tissue engineering.lld:pubmed
pubmed-article:16827593pubmed:affiliationDepartment of Bioengineering, Rice University, MS-142, Houston, Texas 77251-1892, USA.lld:pubmed
pubmed-article:16827593pubmed:publicationTypeJournal Articlelld:pubmed
pubmed-article:16827593pubmed:publicationTypeResearch Support, U.S. Gov't, Non-P.H.S.lld:pubmed
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