Source:http://linkedlifedata.com/resource/pubmed/id/16608348
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
15
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| pubmed:dateCreated |
2006-4-12
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| pubmed:abstractText |
The introduction of bulky substituents at the stereogenic center of light-driven second-generation molecular motors results in an acceleration of the speed of rotation. This is due to a more strained structure with elongated C=C bonds and a higher energy level of the ground state relative to the transition state for the rate-limiting thermal isomerization step. Understanding the profound influence that variation of the substituent at the stereogenic center holds over the rotational speed of the light-driven molecular motor has enabled the development of the fastest molecular motor reported thus far.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Apr
|
| pubmed:issn |
0002-7863
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| pubmed:author | |
| pubmed:issnType |
Print
|
| pubmed:day |
19
|
| pubmed:volume |
128
|
| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
|
| pubmed:pagination |
5127-35
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| pubmed:year |
2006
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| pubmed:articleTitle |
Fine tuning of the rotary motion by structural modification in light-driven unidirectional molecular motors.
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| pubmed:affiliation |
Department of Organic and Molecular Inorganic Chemistry, Stratingh Institute, University of Groningen, Nijenborgh 4, 9747 AG, Groningen, The Netherlands.
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| pubmed:publicationType |
Journal Article
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