Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
1
pubmed:dateCreated
2006-2-23
pubmed:abstractText
The U.S. Environmental Protection Agency's (U.S. EPA) narcosis model requires the measurement of 18 parent and 16 groups of alkyl polycyclic aromatic hydrocarbons (PAHs) (so-called 34 PAHs) in sediments to calculate the number of PAH toxic units (TU) available to benthic organisms. If data for the 34 PAHs are not available, the U.S. EPA proposes estimating the risk by multiplying the TU for 13 parent PAHs by 11.5 (95% confidence interval) based on data from 488 sediments. This estimate is overly conservative for PAHs from pyrogenic manufactured gas plant (MGP) processes based on the analysis of 45 sediments from six sites. Parent PAHs contributed approximately 40% of the total concentrations and TU for MGP sediments. In contrast, parent PAHs from diesel fuel and petroleum crude oil contributed only 2 and 1%, respectively, of the PAH concentrations and TU, compared to approximately 98 to 99% contributed by the alkyl PAHs. Statistical comparison of the TU based on the measured 34 alkyl and parent PAHs and those based on only 13 parent PAHs demonstrated that a factor of 4.2 (rather than 11.5) is sufficient to estimate total TU within a 95% confidence level for MGP sites. Similarly, measurement of parent PAHs is sufficient to accurately estimate the total 34 alkyl and parent PAH concentrations for MGP-impacted sediments.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Jan
pubmed:issn
0730-7268
pubmed:author
pubmed:issnType
Print
pubmed:volume
25
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
287-96
pubmed:dateRevised
2006-11-15
pubmed:meshHeading
pubmed:year
2006
pubmed:articleTitle
Measurement of total polycyclic aromatic hydrocarbon concentrations in sediments and toxic units used for estimating risk to benthic invertebrates at manufactured gas plant sites.
pubmed:affiliation
Energy and Environmental Research Center, University of North Dakota, Box 9018, Grand Forks, North Dakota 58202, USA. shawthorne@undeerc.org
pubmed:publicationType
Journal Article, Research Support, U.S. Gov't, Non-P.H.S., Research Support, Non-U.S. Gov't, Evaluation Studies