Linked Life Data

16117522

Source:http://linkedlifedata.com/resource/pubmed/id/16117522

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
34
pubmed:dateCreated
2005-8-24
pubmed:abstractText
We describe herein the novel application of a transition metal oxo complex, a cationic oxorhenium(V) oxazoline, in the production of molecular hydrogen (H2) from the catalytic hydrolytic oxidation of organosilanes. The main highlights of the reaction are quantitative hydrogen yields, low catalyst loading, ambient conditions, high selectivity for silanols, water as the only co-reagent, and no solvent requirement. The amount of hydrogen produced is proportional to the water stoichiometry. Thus, reaction mixtures of polysilyl organics such as HC(SiH3)3 and water contain potentially >6 wt % hydrogen. Kinetic and isotope labeling experiments have revealed a new mechanistic paradigm for the activation of Si-H bonds by oxometalates.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Aug
pubmed:issn
0002-7863
pubmed:author
pubmed:issnType
Print
pubmed:day
31
pubmed:volume
127
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
11938-9
pubmed:dateRevised
2008-1-17
pubmed:year
2005
pubmed:articleTitle
Hydrogen production from hydrolytic oxidation of organosilanes using a cationic oxorhenium catalyst.
pubmed:affiliation
Brown Laboratory, Department of Chemistry, Purdue University, 560 Oval Drive, West Lafayette, Indiana 47907, USA.
pubmed:publicationType
Journal Article