Linked Life Data

15810814

Source:http://linkedlifedata.com/resource/pubmed/id/15810814

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
14
pubmed:dateCreated
2005-4-6
pubmed:abstractText
para-Hydrogen-induced polarization methods are shown to enable the in situ detection of linear and branched monophosphine-containing intermediates during hydroformylation when Co(eta3-C3H5)(CO)2(PCy3) is the catalyst precursor. The NMR signal characteristics of the alkyl arms of these species provide direct evidence for the rapid interconversion of linear and branched cobalt alkyls prior to the CO insertion step. The observation of additional para-hydrogen-enhanced signals for the corresponding linear and branched aldehydes enables the reactions selectivity to be rapidly monitored as a function of H2 and CO pressure or reaction temperature.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Apr
pubmed:issn
0002-7863
pubmed:author
pubmed:issnType
Print
pubmed:day
13
pubmed:volume
127
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
4994-5
pubmed:dateRevised
2008-1-17
pubmed:year
2005
pubmed:articleTitle
Detection of intermediates in cobalt-catalyzed hydroformylation using para-hydrogen-induced polarization.
pubmed:affiliation
Department of Chemistry, University of York, York YO10 5DD, UK.
pubmed:publicationType
Journal Article