Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
5
pubmed:dateCreated
2005-4-1
pubmed:abstractText
The mixed micelles constituted by a nonionic surfactant widely used in the biochemical field, n-octyl-beta-D-glucopyranoside, and a cationic surfactant with 12 carbon atoms on the hydrophobic tail, dodecyltrimethylammonium bromide, have been studied in aqueous solution, at 298.15 K, by means of conductivity, speed of sound, density, and fluorescence spectroscopy experiments. From these data, the monomeric and micellar phases of the mixed aggregates were fully analyzed through the determination of the total and partial critical micellar concentrations, the dissociation degree of the mixed micelle, the total and partial aggregation numbers, the apparent molar volumes and isentropic compressibilities, the hydration numbers, and the corresponding changes in these thermodynamic properties due to the mixed aggregation process. The experimental findings have been compared with those obtained with several theoretical models, some of them modified in this work to take into account the specific characteristics of the aggregates studied herein.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Mar
pubmed:issn
0743-7463
pubmed:author
pubmed:issnType
Print
pubmed:day
2
pubmed:volume
20
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
1587-96
pubmed:dateRevised
2006-11-15
pubmed:meshHeading
pubmed:year
2004
pubmed:articleTitle
Mixed micellization of a nonionic-cationic surfactant system constituted by n-octyl-beta-D-glucopyranoside/dodecyltrimethylammonium bromide/H2O. An electrochemical, thermodynamic, and spectroscopic study.
pubmed:affiliation
Departamento de Química Fisica I, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, 28040-Madrid, Spain.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't