Linked Life Data

15782266

Source:http://linkedlifedata.com/resource/pubmed/id/15782266

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
7
pubmed:dateCreated
2005-3-22
pubmed:abstractText
Tungsten(VI) oxo-salicylate complexes were prepared in moderate yield (47 to 63%) by the reactions of WOCl4 and two equivalents of either 3-methylsalicylic acid (MesaliH2) or 3,5-di-isopropylsalicylic acid (di-i-PrsaliH2). Performing the reaction in refluxing toluene afforded the two analogous ditungsten complexes 1, [{WO(Mesali)(MesaliH)}2(mu-O)], and 2, [{WO(di-i-Prsali)(di-i-PrsaliH)}2(mu-O)], however in refluxing hexane the mononuclear tungsten complex , [WO(di-i-Prsali)(di-i-PrsaliH)Cl], was isolated. The single crystal X-ray study of revealed a pseudo-octahedral geometry around the tungsten centres. Aerosol assisted chemical vapour deposition of or afforded brown tungsten trioxide thin films. These films were converted to yellow fully oxidised WO3 on annealing in air at 550 degrees C for 30 minutes. The yellow WO3 films demonstrate preferred orientation on the substrate and show interesting functional properties-photo induced hydrophilicity and photocatalytic activity.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Apr
pubmed:issn
1477-9226
pubmed:author
pubmed:issnType
Print
pubmed:day
7
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
1287-93
pubmed:year
2005
pubmed:articleTitle
Synthesis and characterisation of tungsten(VI) oxo-salicylate complexes for use in the chemical vapour deposition of self-cleaning films.
pubmed:affiliation
Department of Chemistry, Christopher Ingold Laboratories, University College London, 20 Gordon Street, London, UKWC1H 0AJ.
pubmed:publicationType
Journal Article