15740111

Source:http://linkedlifedata.com/resource/pubmed/id/15740111

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0007382, umls-concept:C1442756
pubmed:issue	9
pubmed:dateCreated	2005-3-2
pubmed:abstractText	Room-temperature catalytic hydrodefluorination of the strong C(sp3)-F bonds in benzotrifluorides and fluoropentane is catalyzed by Et3Si[B(C6F5)4] and uses Et3SiH as the source of H. Ar-CF3 compounds are converted to Ar-CH3 and fluropentane to pentane. The reaction is thought to proceed via abstraction of F- by Et3Si[B(C6F5)4], and the substituent effects are consistent with this hypothesis.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/7503056
pubmed:status	PubMed-not-MEDLINE
pubmed:month	Mar
pubmed:issn	0002-7863
pubmed:author	pubmed-author:Celenligil-CetinRemleR, pubmed-author:OzerovOleg VOV, pubmed-author:ScottValerie JVJ
pubmed:issnType	Print
pubmed:day	9
pubmed:volume	127
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	2852-3
pubmed:dateRevised	2008-1-17
pubmed:year	2005
pubmed:articleTitle	Room-temperature catalytic hydrodefluorination of C(sp3)-F bonds.
pubmed:affiliation	Department of Chemistry, Brandeis University, MS015, 415 South Street, Waltham Massachusetts 02454, USA.
pubmed:publicationType	Journal Article