Source:http://linkedlifedata.com/resource/pubmed/id/15332900
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rdf:type | |
pubmed:issue |
10
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pubmed:dateCreated |
2004-8-30
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pubmed:abstractText |
Photodissociation dynamics of 1,2-butadiene at 157 nm has been investigated using a molecular beam apparatus based on photoionization using vacuum ultraviolet synchrotron radiation. Six dissociation pathways have been observed. The observed channels are C4H5+H, C4H4+H2, C3H3+CH3, C2H3+C2H3, C2H4+C2H2, and C4H4+H+H. Among all the dissociation channels, the C3H3+CH3 channel is found to be the dominant process. The product kinetic energy distributions of all dissociation channels have been determined from simulating the experimental time-of-flight spectra. Relative branching ratios for all observed dissociation channels were also estimated based on all detected products.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:status |
PubMed-not-MEDLINE
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pubmed:month |
Sep
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pubmed:issn |
0021-9606
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pubmed:author | |
pubmed:copyrightInfo |
Copyright 2004 American Institute of Physics
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pubmed:issnType |
Print
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pubmed:day |
8
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pubmed:volume |
121
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
4684-90
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pubmed:year |
2004
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pubmed:articleTitle |
Photodissociation dynamics of 1,2-butadiene at 157 nm.
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pubmed:affiliation |
State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Science, Dalian 116023, People's Republic of China.
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pubmed:publicationType |
Journal Article
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