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PredicateObject
rdf:type
pubmed:issue
10
pubmed:dateCreated
2004-8-30
pubmed:abstractText
Photodissociation dynamics of 1,2-butadiene at 157 nm has been investigated using a molecular beam apparatus based on photoionization using vacuum ultraviolet synchrotron radiation. Six dissociation pathways have been observed. The observed channels are C4H5+H, C4H4+H2, C3H3+CH3, C2H3+C2H3, C2H4+C2H2, and C4H4+H+H. Among all the dissociation channels, the C3H3+CH3 channel is found to be the dominant process. The product kinetic energy distributions of all dissociation channels have been determined from simulating the experimental time-of-flight spectra. Relative branching ratios for all observed dissociation channels were also estimated based on all detected products.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Sep
pubmed:issn
0021-9606
pubmed:author
pubmed:copyrightInfo
Copyright 2004 American Institute of Physics
pubmed:issnType
Print
pubmed:day
8
pubmed:volume
121
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
4684-90
pubmed:year
2004
pubmed:articleTitle
Photodissociation dynamics of 1,2-butadiene at 157 nm.
pubmed:affiliation
State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Science, Dalian 116023, People's Republic of China.
pubmed:publicationType
Journal Article