Source:http://linkedlifedata.com/resource/pubmed/id/15230613
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
14
|
| pubmed:dateCreated |
2004-7-2
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| pubmed:abstractText |
The mechanism for the unusual AlCl(3)-catalyzed rearrangement of 2,2-dichloronorbornane to 1-chloronorbornane in pentane has been elucidated; the reaction, which also yields four isomeric dichloronorbornanes, occurs in three steps: (1). ionization to form the 2-chloro-2-norbornyl cation, which was fully characterized by two-dimensional (1)H and (13)C NMR in SbF(5)/SO(2)ClF; (2). Wagner-Meerwein shift to yield the 1-chloro-2-norbornyl cation, which was partially characterized by (1)H NMR; and (3). hydride abstraction.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
|
| pubmed:month |
Jul
|
| pubmed:issn |
0022-3263
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| pubmed:author | |
| pubmed:issnType |
Print
|
| pubmed:day |
9
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| pubmed:volume |
69
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| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
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| pubmed:pagination |
4843-4
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| pubmed:year |
2004
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| pubmed:articleTitle |
Lewis acid-catalyzed rearrangement of 2,2-dichloronorbornane to 1-chloronorbornane.
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| pubmed:affiliation |
Department of Chemistry, University of Tennessee, Knoxville, Tennessee 37996-1600, USA.
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| pubmed:publicationType |
Journal Article
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