Source:http://linkedlifedata.com/resource/pubmed/id/14682756
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
26
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pubmed:dateCreated |
2003-12-19
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pubmed:abstractText |
The synthesis of diaryloxydiazirines, precursors to diaryloxycarbenes, is described. Thermolyses of the diazirines afford anticipated carbene products, but photolyses afford both carbenes and aryloxy radicals by alpha-scission. UV spectra of the carbenes and radicals are observed. [reaction: see text]
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pubmed:language |
eng
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pubmed:journal | |
pubmed:status |
PubMed-not-MEDLINE
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pubmed:month |
Dec
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pubmed:issn |
1523-7060
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:day |
25
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pubmed:volume |
5
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
5027-30
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pubmed:year |
2003
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pubmed:articleTitle |
Aryloxy radicals from diaryloxydiazirines: alpha-cleavage of diaryloxycarbenes or excited diazirines?
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pubmed:affiliation |
Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, New Brunswick, NJ 08903, USA.
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pubmed:publicationType |
Journal Article
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