14680252

Source:http://linkedlifedata.com/resource/pubmed/id/14680252

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0024485, umls-concept:C0205223, umls-concept:C0220781, umls-concept:C0220853, umls-concept:C0333051, umls-concept:C0337189, umls-concept:C0441239, umls-concept:C0678594, umls-concept:C1883254
pubmed:issue	23
pubmed:dateCreated	2003-12-18
pubmed:abstractText	[Na11(OtBu)10(OH)], a hydroxide enclosing 21-vertex cage compound, was found to crystallize from mixtures of sodium tert.butanolate with sodium hydroxide. Its structure can be derived from the known (NaOtBu)6-hexaprismane by replacing one butanolate unit with OH- and capping the latter with five additional units of NaOtBu. The hydroxide shows a signal at -3.21 ppm in the 1H NMR spectrum.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/9610838
pubmed:status	PubMed-not-MEDLINE
pubmed:month	Dec
pubmed:issn	1359-7345
pubmed:author	pubmed-author:GeierJensJ, pubmed-author:GrützmacherHansjörgH
pubmed:issnType	Print
pubmed:day	7
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	2942-3
pubmed:year	2003
pubmed:articleTitle	Synthesis and structure of [Na11(OtBu)10(OH)]: 1H NMR shift of a hydroxide ion encapsulated in a 21-vertex alcoholate cage.
pubmed:affiliation	Department of Chemistry and Applied Biology, HCI, ETH Hönggerberg, Zürich, Switzerland.
pubmed:publicationType	Journal Article