Source:http://linkedlifedata.com/resource/pubmed/id/14505396
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
39
|
| pubmed:dateCreated |
2003-9-24
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| pubmed:abstractText |
The square-planar structure of a diamagnetic Cu(III) complex of tetrakis(pentafluorophenyl)-substituted N-confused porphyrin was elucidated by X-ray diffraction analysis. The facile interconversion between Cu(II) (1) and Cu(III) (2) complexes was achieved by chemical oxidation/reduction, and the Cu(III)/Cu(II) redox potential was controlled by adding anions through the hydrogen-bonding interaction to the peripheral NH.
|
| pubmed:language |
eng
|
| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
|
| pubmed:month |
Oct
|
| pubmed:issn |
0002-7863
|
| pubmed:author | |
| pubmed:issnType |
Print
|
| pubmed:day |
1
|
| pubmed:volume |
125
|
| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
|
| pubmed:pagination |
11822-3
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| pubmed:dateRevised |
2008-1-17
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| pubmed:year |
2003
|
| pubmed:articleTitle |
Control of Cu(II) and Cu(III) states in N-confused porphyrin by protonation/deprotonation at the peripheral nitrogen.
|
| pubmed:affiliation |
Department of Chemistry, Graduate School of Science, Kyoto University, Kyoto 606-8502, Japan.
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| pubmed:publicationType |
Journal Article
|