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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
12
|
| pubmed:dateCreated |
1993-4-15
|
| pubmed:abstractText |
Metabolism in vivo of 2,4,3',4'-tetrachlorobiphenyl (TCB) was further studied using male Wistar rats. When the extract of feces of rats given TCB with chloroform was methylated and applied to gas chromatography (GC)-mass spectrometry (MS), a new metabolite was detected. The structure of this new metabolite was 4-hydroxy-2,5,3'4'-TCB based on both its retention time in GC and comparison of the mass spectrum with that of the synthetic sample. 4-Hydroxy-2,5,3',4'-TCB was assumed to be formed via a 4,5-oxide intermediate followed by NIH-shift of a chlorine atom at 4-position.
|
| pubmed:language |
eng
|
| pubmed:journal | |
| pubmed:citationSubset |
IM
|
| pubmed:chemical | |
| pubmed:status |
MEDLINE
|
| pubmed:month |
Dec
|
| pubmed:issn |
0009-2363
|
| pubmed:author | |
| pubmed:issnType |
Print
|
| pubmed:volume |
40
|
| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
|
| pubmed:pagination |
3338-9
|
| pubmed:dateRevised |
2006-11-15
|
| pubmed:meshHeading |
pubmed-meshheading:1294337-Animals,
pubmed-meshheading:1294337-Biotransformation,
pubmed-meshheading:1294337-Feces,
pubmed-meshheading:1294337-Male,
pubmed-meshheading:1294337-Methylation,
pubmed-meshheading:1294337-Polychlorinated Biphenyls,
pubmed-meshheading:1294337-Rats,
pubmed-meshheading:1294337-Rats, Wistar
|
| pubmed:year |
1992
|
| pubmed:articleTitle |
A new metabolite of 2,4,3',4'-tetrachlorobiphenyl in rat feces.
|
| pubmed:affiliation |
Department of Food and Nutrition, Nakamura Gakuen College, Fukuoka, Japan.
|
| pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
|