Source:http://linkedlifedata.com/resource/pubmed/id/12848547
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
28
|
| pubmed:dateCreated |
2003-7-9
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| pubmed:abstractText |
Iron(II) complexes bearing monoanionic tridentate salicyladiminato ligands are shown to be highly efficient catalysts for atom transfer radical polymerization (ATRP). Polymerization rates for styrene are among the highest reported for iron-mediated ATRP in nonpolar media, correlating well with E1/2 potentials and DeltaEp values for the complexes. The rigidity of the tridentate ligands, combined with ample space around the metal center to accommodate a halogen atom, we believe to be an important factor in the efficient ATRP behavior of these systems.
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| pubmed:language |
eng
|
| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
|
| pubmed:month |
Jul
|
| pubmed:issn |
0002-7863
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| pubmed:author | |
| pubmed:issnType |
Print
|
| pubmed:day |
16
|
| pubmed:volume |
125
|
| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
|
| pubmed:pagination |
8450-1
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| pubmed:dateRevised |
2008-1-17
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| pubmed:year |
2003
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| pubmed:articleTitle |
Design of highly active iron-based catalysts for atom transfer radical polymerization: tridentate salicylaldiminato ligands affording near ideal Nernstian behavior.
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| pubmed:affiliation |
Department of Chemistry, Imperial College London, Exhibition Road, South Kensington, London, UK, SW7 2AZ.
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| pubmed:publicationType |
Journal Article
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