Source:http://linkedlifedata.com/resource/pubmed/id/12510291
Switch to
Predicate | Object |
---|---|
rdf:type | |
lifeskim:mentions | |
pubmed:issue |
22
|
pubmed:dateCreated |
2003-1-3
|
pubmed:abstractText |
Hitherto unknown, relatively labile gem-difluorinated vinyloxiranes were prepared by difluoro-Wittig reactions with alpha,beta-epoxyketones; for these vinyloxiranes alkyl groups were delivered at the fluorine-attached terminal carbon atom in an SN2' manner by RLi, while Me3Al and MeMgBr-CuCl (3: 1) introduced the Me group at the allylic epoxy carbon with retention and inversion of the original stereochemistry, respectively.
|
pubmed:language |
eng
|
pubmed:journal | |
pubmed:status |
PubMed-not-MEDLINE
|
pubmed:month |
Nov
|
pubmed:issn |
1359-7345
|
pubmed:author | |
pubmed:issnType |
Print
|
pubmed:day |
21
|
pubmed:owner |
NLM
|
pubmed:authorsComplete |
Y
|
pubmed:pagination |
2670-1
|
pubmed:dateRevised |
2003-11-4
|
pubmed:year |
2002
|
pubmed:articleTitle |
Preparation and regioselective reactions of novel gem-difluorinated vinyloxiranes with some organometallic reagents.
|
pubmed:affiliation |
Graduate School of Bioscience and Bioengineering, Tokyo Institute of Technology, 4259 Nagatsuta-cho, Midori-ku, Yokohama 226-8501, Japan.
|
pubmed:publicationType |
Journal Article
|