Linked Life Data

12457952

Source:http://linkedlifedata.com/resource/pubmed/id/12457952

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
1
pubmed:dateCreated
2002-11-29
pubmed:abstractText
The reaction of 5H,5Cl-dibenzo[a,d]cycloheptatriene with nitrobenzene was investigated under both thermal (210 degrees C) and ultrasonic (50 degrees C, 40 kHz) activation. The reaction products of both procedures are similar, but their amounts depend on the activation source. To account for the products a common electron transfer reaction is postulated through the dibenzotropylium cation. The differences between the thermal and ultrasonic process is thought to arise from the role of nitrobenzene as oxidant. Under thermal conditions this occurs throughout the reaction mixture but under sonication it occurs only in the cavitation bubble and in its immediate vicinity.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Jan
pubmed:issn
1350-4177
pubmed:author
pubmed:issnType
Print
pubmed:volume
10
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
49-53
pubmed:dateRevised
2003-11-4
pubmed:year
2003
pubmed:articleTitle
A comparison between the sonochemical and thermal reaction of 5H,5Cl-dibenz[a,d]cycloheptatriene with nitrobenzene.
pubmed:affiliation
C.D. Nenitzescu, Institute of Organic Chemistry, Romanian Academy, C.P. 254, P.O. Box 15-254, 71141 Bucharest, Romania.
pubmed:publicationType
Journal Article