Linked Life Data

12137549

Source:http://linkedlifedata.com/resource/pubmed/id/12137549

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
30
pubmed:dateCreated
2002-7-24
pubmed:abstractText
Oxidized carbon nanotubes have been reacted with Wilkinson's complex. It has been found that the Rh metal coordinates to these nanotubes through the increased number of oxygen atoms, forming a hexacoordinate structure around the Rh atom. The reaction process increases oxidized nanotube solubility in DMSO (>150 mg/L) as well as to a certain extent in DMF and THF. The functionalization process results in exfoliation of larger bundles of SWNTs and may select for the presence of distributions of smaller-diameter tubes. Optical data on the derivatized adducts suggest the possibility of interesting charge-transfer behavior across the metal-nanotube interface. An application has been made of this system as supports for homogeneous catalysis.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Jul
pubmed:issn
0002-7863
pubmed:author
pubmed:issnType
Print
pubmed:day
31
pubmed:volume
124
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
8940-8
pubmed:dateRevised
2003-11-3
pubmed:year
2002
pubmed:articleTitle
Structural characterization, optical properties, and improved solubility of carbon nanotubes functionalized with Wilkinson's catalyst.
pubmed:affiliation
Department of Chemistry, State University of New York at Stony Brook, Stony Brook, New York 11794, USA.
pubmed:publicationType
Journal Article