Source:http://linkedlifedata.com/resource/pubmed/id/12121080
Switch to
| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
29
|
| pubmed:dateCreated |
2002-7-17
|
| pubmed:abstractText |
A new ionic complex of C60 with decamethylchromocene, Cp*2Cr.C60(C6H4Cl2)2 (1), has been obtained. The fullerides are monomeric in 1 at room temperature, whereas they form a single-bonded (C60-)2 dimer at low temperatures, the structure of which has been studied by the X-ray diffraction on a single crystal at 100 K. The length of the intercage C-C bond is 1.597(7) A and the interfullerene distance is equal to 9.28 A. A phase transition attributed to the reversible C60*- dimerization is observed in the 220-200 K range. The transition is accompanied by changes in the unit cell parameters, the decrease of the magnetic moment from 4.20 muB (S = 3/2, 1/2) to 3.88 muB (S = 3/2) and the appearance of EPR signal from Cp*2Cr+, simultaneously.
|
| pubmed:language |
eng
|
| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
|
| pubmed:month |
Jul
|
| pubmed:issn |
0002-7863
|
| pubmed:author | |
| pubmed:issnType |
Print
|
| pubmed:day |
24
|
| pubmed:volume |
124
|
| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
|
| pubmed:pagination |
8520-1
|
| pubmed:dateRevised |
2008-1-17
|
| pubmed:year |
2002
|
| pubmed:articleTitle |
The reversible formation of a single-bonded (C(60)(-))(2) dimer in ionic charge transfer complex: Cp*(2)Cr.C(60)(C(6)H(4)Cl(2))(2). The molecular structure of (C(60)(-))(2).
|
| pubmed:affiliation |
Division of Chemistry, Graduate School of Science, Kyoto University, Sakyo-ku, Kyoto 606-8502, Japan. konarev@icp.ac.ru
|
| pubmed:publicationType |
Journal Article
|