Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
5
pubmed:dateCreated
2002-6-28
pubmed:abstractText
Sorption studies of chromate on weakly basic macroporous anion exchanger Amberlyst A-21 were performed as a function of pH (2 - 9), temperature (20 - 40 degrees C) and concentration (0.4 - 80 mmol.l(-1)). Chromate sorption was observed to decrease with the increase in initial pH of the solution, with a sorption maxima at pH 2 and increased with the increase in temperature. The changes in pH and in the ratio of choride ions released to chromate ions sorbed suggested that the anion exchange process was accomanied by hydrolysis and Donnan invasion. The FTIR spectra and isoeteric heat of sorption besides showing the hydrolysis / Donnan invasion of resin under different experimental conditions of concentration, pH and temperature also showed the dimerization of the chromate species inside the resin phase.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
May
pubmed:issn
0959-3330
pubmed:author
pubmed:issnType
Print
pubmed:volume
23
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
583-90
pubmed:dateRevised
2007-3-21
pubmed:meshHeading
pubmed:year
2002
pubmed:articleTitle
Selective removal of chromates by macroporous exchanger Amberlyst A-21.
pubmed:affiliation
National Centre of Excellence in Physical Chemistry, University of Peshawar, Pakistan.
pubmed:publicationType
Journal Article