Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
7
pubmed:dateCreated
2002-6-4
pubmed:abstractText
Several methods were tested to optimise sulphate reduction and minimise methane formation in thermophilic (65 degrees) expanded granular sludge bed reactors fed with a medium containing sulphate and methanol. Lowering the pH from 7.5 to 6.75 resulted in a rapid decrease of methane formation and a concomitant increase in sulphate reduction. The inhibition of methane formation was irreversible on the short-term. Lowering the COD/SO4(2-) ratio (COD: chemical oxygen demand) from 6 to 0.34 (g/g) rapidly favoured sulphate reduction over methanogenesis. Continuous addition of 2 g L(-1) 2-bromoethanesulphonate was ineffective as complete inhibition of methanogenesis was obtained only for two days. Inhibition of methanogens by sulphide at pH 7.5 was only effective when the total sulphide concentration was above 1200 mg S L(-1). For practical applications, a relatively short exposure to a slightly acidic pH in combination with operating the reactor at a volumetric methanol-COD loading rate close to the maximum volumetric sulphide-COD formation rate.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Apr
pubmed:issn
0043-1354
pubmed:author
pubmed:issnType
Print
pubmed:volume
36
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
1825-33
pubmed:dateRevised
2006-11-15
pubmed:meshHeading
pubmed:year
2002
pubmed:articleTitle
Optimisation of sulphate reduction in a methanol-fed thermophilic bioreactor.
pubmed:affiliation
Sub-department Environmental Technology, Wageningen University, The Netherlands. jan.weijma@algemeen.mt.wag-ur.nl
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't