Source:http://linkedlifedata.com/resource/pubmed/id/11870294
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
Pt 3
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| pubmed:dateCreated |
2002-3-6
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| pubmed:abstractText |
The title compound, bis(dimethyl sulfoxide)triiodothallium(III), [TlI(3)(C(2)H(6)OS)(2)], was crystallized from equimolar amounts of Tl(I)I and I(2) in a dimethyl sulfoxide (DMSO) solution. After the initial redox reaction, the thallium(III)-iodo complex forms and precipitates as a DMSO solvate. In the crystal structure, Tl is surrounded by three iodide ligands in the equatorial plane and two O-coordinated DMSO molecules in the axial positions, forming a slightly distorted trigonal bipyramid. The complex lies on a twofold rotation axis, making the DMSO molecules and two of the I atoms crystallographically equivalent.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Mar
|
| pubmed:issn |
0108-2701
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| pubmed:author | |
| pubmed:issnType |
Print
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| pubmed:volume |
58
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
m177-8
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| pubmed:dateRevised |
2003-11-3
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| pubmed:year |
2002
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| pubmed:articleTitle |
The trigonal-bipyramidal triiodothallium(III) complex [TlI(3)[(CH(3))(2)SO]2].
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| pubmed:affiliation |
Department of Chemistry, Shanxi University, Taiyuan 030006, People's Republic of China.
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| pubmed:publicationType |
Journal Article
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