Linked Life Data

11843611

Source:http://linkedlifedata.com/resource/pubmed/id/11843611

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
4
pubmed:dateCreated
2002-2-14
pubmed:abstractText
[reaction: see text] A double ring-closing metathesis reaction for the efficient construction of the fused bicyclic izidine alkaloid skeleton was developed. In this reaction, high selectivity was realized by tuning of electronic and steric effects of substituents in the N-containing tetraenes. It was observed that the reactivity of electron-rich carbon-carbon double bonds is higher than that of electron-deficient ones. A brief mechanistic study is also discussed.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Feb
pubmed:issn
1523-7060
pubmed:author
pubmed:issnType
Print
pubmed:day
21
pubmed:volume
4
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
639-41
pubmed:dateRevised
2003-11-3
pubmed:year
2002
pubmed:articleTitle
Unexpected dramatic substituent effect for tuning the selectivity in the double ring-closing metathesis reaction of N-containing tetraenes. An efficient synthesis of bicyclic izidine alkaloid skeletons.
pubmed:affiliation
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, PR China. masm@pub.sioc.ac.cn
pubmed:publicationType
Journal Article