Source:http://linkedlifedata.com/resource/pubmed/id/11541740
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rdf:type | |
lifeskim:mentions | |
pubmed:dateCreated |
1999-5-29
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pubmed:abstractText |
Flow injection analysis instrumentation and methodology for the determination of ammonia and ammonium ions in an aqueous solution are described. Using in-line solid phase basification beds containing crystalline media. the speciation of ammoniacal nitrogen is shifted toward the un-ionized form. which diffuses in the gas phase across a hydrophobic microporous hollow fiber membrane into a pure-water-containing analytical stream. The two streams flow in a countercurrent configuration on opposite sides of the membrane. The neutral pH of the analytical stream promotes the formation of ammonium cations, which are detected using specific conductance. The methodology provides a lower limit of detection of 10 microgram/L and a dynamic concentration range spanning three orders of magnitude using a 315-microliters sample injection volume. Using immobilized urease to enzymatically promote the hydrolysis of urea to produce ammonia and carbon dioxide, the technique has been extended to the determination of urea.
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pubmed:keyword | |
pubmed:language |
eng
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pubmed:citationSubset |
S
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pubmed:chemical |
http://linkedlifedata.com/resource/pubmed/chemical/Ammonia,
http://linkedlifedata.com/resource/pubmed/chemical/Ammonium Chloride,
http://linkedlifedata.com/resource/pubmed/chemical/Magnesium Oxide,
http://linkedlifedata.com/resource/pubmed/chemical/Membranes, Artificial,
http://linkedlifedata.com/resource/pubmed/chemical/Sewage,
http://linkedlifedata.com/resource/pubmed/chemical/Urea,
http://linkedlifedata.com/resource/pubmed/chemical/Urease
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pubmed:status |
MEDLINE
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pubmed:author | |
pubmed:owner |
NASA
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pubmed:authorsComplete |
Y
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pubmed:pagination |
372-82
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pubmed:dateRevised |
2007-7-17
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pubmed:meshHeading |
pubmed-meshheading:11541740-Ammonia,
pubmed-meshheading:11541740-Ammonium Chloride,
pubmed-meshheading:11541740-Flow Injection Analysis,
pubmed-meshheading:11541740-Hydrogen-Ion Concentration,
pubmed-meshheading:11541740-Hydrolysis,
pubmed-meshheading:11541740-Magnesium Oxide,
pubmed-meshheading:11541740-Membranes, Artificial,
pubmed-meshheading:11541740-Sewage,
pubmed-meshheading:11541740-Spectrophotometry,
pubmed-meshheading:11541740-Temperature,
pubmed-meshheading:11541740-Urea,
pubmed-meshheading:11541740-Urease
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pubmed:articleTitle |
"Reagentless" flow injection determination of ammonia and urea using membrane separation and solid phase basification.
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pubmed:affiliation |
UMPQUA Research Company, Myrtle Creek, Oregon 97457, USA.
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pubmed:publicationType |
Journal Article,
Comparative Study,
Research Support, U.S. Gov't, Non-P.H.S.
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