Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
2
pubmed:dateCreated
1995-8-8
pubmed:abstractText
The Precambrian record of carbonate and evaporite sedimentation is equivocal. In contrast to most previous interpretations, it is possible that Archean, Paleoproterozoic, and to a lesser extent, Meso to Neoproterozoic seawater favored surplus abiotic carbonate precipitation, as aragonite and (hi-Mg?) calcite, in comparison to younger times. Furthermore, gypsum/anhydrite may have been only rarely precipitated prior to halite precipitation during evaporation prior to about 1.8 Ga. Two effects may have contributed to these relationships. First, sulfate concentration of seawater may have been critically low prior to about 1.9 Ga so the product mCa++ x mSO4-- would not have produced gypsum before halite, as in the Mesoproterozoic to modern ocean. Second, the bicarbonate to calcium ratio was sufficiently high so that during progressive evaporation of seawater, calcium would have been exhausted before the gypsum field was reached. The pH of the Archean and Paleoproterozoic ocean need not have been significantly different from the modern value of 8.1, even at CO2 partial pressures of a tenth of an atmosphere. Higher CO2 partial pressures require somewhat lower pH values.
pubmed:keyword
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
S
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Mar
pubmed:issn
0022-1376
pubmed:author
pubmed:issnType
Print
pubmed:volume
101
pubmed:owner
NASA
pubmed:authorsComplete
Y
pubmed:pagination
235-43
pubmed:dateRevised
2010-11-18
pubmed:meshHeading
pubmed:year
1993
pubmed:articleTitle
New constraints on Precambrian ocean composition.
pubmed:affiliation
Department of Earth, Atmospheric and Planetary Sciences, Massachusetts Institute of Technology, Cambridge 02139.
pubmed:publicationType
Journal Article, Research Support, U.S. Gov't, P.H.S., Research Support, U.S. Gov't, Non-P.H.S.