Source:http://linkedlifedata.com/resource/pubmed/id/11384269
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
20
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pubmed:dateCreated |
2001-5-31
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pubmed:abstractText |
Anion-yield spectroscopy using x rays is shown to be a selective probe of molecular core-level processes, providing unique experimental verification of shape resonances. For CO, partial anion and cation yields are presented for photon energies near the C K edge. The O- yield exhibits features above threshold related only to doubly excited states, in contrast to cation yields which also exhibit pronounced structure due to the well-known sigma* shape resonance. Because the shape resonance is completely suppressed for O-, anion spectroscopy thus constitutes a highly selective probe, yielding information unobtainable with absorption or electron spectroscopy.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:status |
PubMed-not-MEDLINE
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pubmed:month |
May
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pubmed:issn |
0031-9007
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:day |
14
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pubmed:volume |
86
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
4504-7
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pubmed:dateRevised |
2003-10-31
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pubmed:year |
2001
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pubmed:articleTitle |
Anionic photofragmentation of CO: a selective probe of core-level resonances.
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pubmed:affiliation |
Department of Chemistry, University of Nevada, Las Vegas, Nevada 89154-4003, USA.
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pubmed:publicationType |
Journal Article
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