Source:http://linkedlifedata.com/resource/pubmed/id/11313569
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| Predicate | Object |
|---|---|
| rdf:type | |
| pubmed:issue |
Pt 4
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| pubmed:dateCreated |
2001-4-23
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| pubmed:abstractText |
The crystal and molecular structure of the title compound, (CH(7)N(4))(CH(8)N(4))[SbCl(6)], has been determined at 295 and 92 K. It is composed of isolated [SbCl(6)](3-) octahedra and aminoguanidinium mono- and dications. One of four of the crystallographically inequivalent aminoguanidinium cations is disordered at both temperatures. Two crystallographically inequivalent [SbCl(6)](3-) octahedra were found to possess three significantly longer Sb-Cl bonds than three other octahedra. The shorter bonds are in the range 2.456 (2)-2.577 (2) A, whereas the longer ones are between 2.705 (2) and 2.931 (2) A. Each short Sb-Cl bond is located trans to a long bond. It is argued that this deformation is caused by N-H.Cl hydrogen bonds.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Apr
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| pubmed:issn |
0108-2701
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| pubmed:author | |
| pubmed:issnType |
Print
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| pubmed:volume |
57
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
388-91
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| pubmed:dateRevised |
2003-10-31
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| pubmed:year |
2001
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| pubmed:articleTitle |
Aminoguanidinium(2+) aminoguanidinium(1+) hexachloroantimonate(III) at 295 and 92 K.
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| pubmed:affiliation |
Institute of Chemistry, University of Opole, Oleska 48, 45-052 Opole, Poland.
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| pubmed:publicationType |
Journal Article
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