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Predicate | Object |
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
7
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pubmed:dateCreated |
1998-6-30
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pubmed:abstractText |
The gum from Anadenanthera colubrina consists mainly of a complex high-arabinose heteropolysaccharide with a (1-->3)-linked beta-D-Galp main-chain and many different side-chains. These contain beta-D-Galp-[(1-->6)-beta-D-Galp]m-(1-->6)-, substituted in turn at O-3 by alpha-L-Araf-[(1-->3)-alpha-L-Araf-]0-2. Also present are (1) main-chain units substituted at O-4 and O-6 by alpha-L-Araf units, (2) side-chains of Rhap-(1-->4)-beta-D-GlcpA-(1-->6)-beta-Galp-groups, (3) alpha-L-Arap non-reducing end-units linked (1-->6) to D-Galp, and (4) beta-Araf and beta-Arap structures. For the first time, a plant gum exudate was found to contain in the natural state, reducing low M(r) carbohydrates. These were rhamnose (0.6%), arabinose (4.7%), mannose (0.1%), galactose (0.8%) and many oligosaccharides (0.6%; 11 with different RFs, with the majority containing arabinose). They were all mixtures with the exception of alpha-Rhap-(1-->4)-beta-D-GlcpA-(1-->6)-alpha beta-Gal and an incompletely identified hexasaccharide, probably having alpha-L-Araf-(1-->4)-beta-D-Galp- and -alpha-L-Araf-(1-->3)-beta-D-Galp- structures. The mono- and oligosaccharides do not appear to arise via in situ autohydrolysis of the gum.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical | |
pubmed:status |
MEDLINE
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pubmed:month |
Apr
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pubmed:issn |
0031-9422
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:volume |
47
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
1207-14
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pubmed:dateRevised |
2001-11-28
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pubmed:meshHeading |
pubmed-meshheading:9611824-Carbohydrate Conformation,
pubmed-meshheading:9611824-Carbohydrate Sequence,
pubmed-meshheading:9611824-Fabaceae,
pubmed-meshheading:9611824-Magnetic Resonance Spectroscopy,
pubmed-meshheading:9611824-Molecular Sequence Data,
pubmed-meshheading:9611824-Monosaccharides,
pubmed-meshheading:9611824-Oligosaccharides,
pubmed-meshheading:9611824-Plants, Medicinal,
pubmed-meshheading:9611824-Polysaccharides,
pubmed-meshheading:9611824-Stereoisomerism
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pubmed:year |
1998
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pubmed:articleTitle |
Gum heteropolysaccharide and free reducing mono- and oligosaccharides of Anadenanthera colubrina.
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pubmed:affiliation |
Departamento de Bioquímica, Universidade Federal do Paraná, Curitiba-PR, Brazil.
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pubmed:publicationType |
Journal Article
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