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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
1-2
|
| pubmed:dateCreated |
1998-3-26
|
| pubmed:abstractText |
Spin-7/2 central line intensities are calculated for any ratio of the quadrupolar coupling constant to the radiofrequency field for both one-pulse and two-pulse Hahn-echo experiments and tested by 59Co NMR on the model compounds, Na3[Co(NO2)6] and trans-[Co(en)2(NO2)2]NO3. The Hahn-echo sequence is then used to obtain the quadrupole coupling constant and asymmetry parameter on a powder sample of Co4(CO)12. This technique is found to be particularly useful when the NMR spectrum is broad and featureless.
|
| pubmed:language |
eng
|
| pubmed:journal | |
| pubmed:citationSubset |
IM
|
| pubmed:chemical | |
| pubmed:status |
MEDLINE
|
| pubmed:month |
Dec
|
| pubmed:issn |
0926-2040
|
| pubmed:author | |
| pubmed:issnType |
Print
|
| pubmed:volume |
10
|
| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
|
| pubmed:pagination |
95-103
|
| pubmed:dateRevised |
2006-11-15
|
| pubmed:meshHeading | |
| pubmed:year |
1997
|
| pubmed:articleTitle |
Spin-7/2 nutation and Hahn-echo amplitudes in model compounds and application to the tetrahedral cluster Co4(CO)12.
|
| pubmed:affiliation |
Institut de chimie, UMR 50 CNRS, Bruker Spectrospin, Université Louis Pasteur, Strasbourg, France.
|
| pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
|