Linked Life Data

9299733

Source:http://linkedlifedata.com/resource/pubmed/id/9299733

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
1-2
pubmed:dateCreated
1997-10-21
pubmed:abstractText
The stability of four pesticides (desethylatrazine, fenamiphos, fenitrothion and fonofos) was examined under different storage conditions after preconcentration in disposable solid-phase extraction (SPE) cartridges containing new polymer sorbent materials (Hysphere-1, IST EnviroLut and LiChrolut). Complete recovery for all the compounds was observed in precolumns kept at -20 degrees C for 1 month when preconcentrating 26 ml of ground water sample spiked at 10 micrograms/l. Degradation of fenamiphos and fenitrothion occurred in precolumns stored at 4 degrees C and at room temperature after 1 month. Fonofos was stable when compared to their storage in C18 precolumns. Problems in the quantification of the analytes after storage at 4 degrees C and at room temperature were encountered due to the presence of many interfering peaks in the chromatograms. Analysis of blanks with C18 precolumns was carried out, to determine the interferences. The stability of the pesticides was also examined in acidifed and non-acidified ground water in order to compare it to the stability of pesticides stored on SPE cartridges. Significant losses of fenamiphos and fenitrothion were achieved and were related to the pH of the water sample and their chemical structure. Finally, the new polymeric sorbent Hysphere-I was evaluated in terms of breakthroughs and compared with those of C18, obtaining higher recoveries for desethylatrazine.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Aug
pubmed:issn
0021-9673
pubmed:author
pubmed:issnType
Print
pubmed:day
22
pubmed:volume
778
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
161-70
pubmed:dateRevised
2009-1-15
pubmed:meshHeading
pubmed:year
1997
pubmed:articleTitle
Stability of pesticides stored on polymeric solid-phase extraction cartridges.
pubmed:affiliation
Department of Environmental Chemistry, CID-CSIC, Barcelona, Spain.
pubmed:publicationType
Journal Article, Comparative Study, Research Support, Non-U.S. Gov't