Linked Life Data

8936421

Source:http://linkedlifedata.com/resource/pubmed/id/8936421

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
1
pubmed:dateCreated
1996-12-31
pubmed:abstractText
A new sulfonamide, 8-quinolinsulfonamide(Hsa), has been prepared and examined as a chelating agent towards metal(II) ions. The spectroscopic properties of the M(II) sulfonamidato complexes has been studied. The inhibitory properties of the ligand and the synthesised complexes were tested. The crystal structure of the [Zn(sa)2(NH3)].NH3 complex was determined by single-crystal X-ray diffraction. Crystal data of the zinc(II) complex: a = 16.217(4)A, b = 8.041(1)A, c = 15.606(4)A, beta = 95.75(1) degrees, Z = 4, and V = 2024.6(7)A3. The refinement of the structure based on 6047 reflections attained to R = 0.049 and Rw = 0.052. The zinc(II) ion is surrounded by four N atoms of two sulfonamidato ligands and one N atom of an ammonia molecule in an trigonal bipyramid arrangement.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Apr
pubmed:issn
0162-0134
pubmed:author
pubmed:issnType
Print
pubmed:volume
62
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
31-9
pubmed:dateRevised
2000-12-18
pubmed:meshHeading
pubmed:year
1996
pubmed:articleTitle
Synthesis and characterization of metal(II)-8-quinolinsulfonamidato (sa-) complexes (M = Co, Ni, Cu, and Zn). Crystal structure of [Zn(sa)2(NH3)]NH3 complex. Carbonic anhydrase inhibitory properties.
pubmed:affiliation
Departamento de Química Inorgánica, Universidad de Valencia, Spain.
pubmed:publicationType
Journal Article