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Predicate | Object |
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
10
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pubmed:dateCreated |
1997-2-4
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pubmed:abstractText |
A new reagent, 1-(9-anthracenylmethyl)piperzine (MAP), was used for the derivatization of airborne 1,6-hexamethylene diisocyanate (HDI) and polyisocyanates generated during spray-painting operations. The new reagent, which offers enhanced sensitivity and uniformity of response to both the monomeric and oligomeric forms of HDI, was compared directly with 1-(2-methoxyphenyl)piperazine (MOP), the currently employed derivatizing reagent used in the National Institute for Occupational Safety and Health Method 5521. Both the validity of the side-by-side sampling protocol and the efficacy of two derivatizing reagents were evaluated in field studies. The analytical results indicate that there is no significant difference at the 95% confidence level in the concentration of polyisocyanate in the aerosol as determined by two impingers containing MAP and a third containing MOP when these are positioned in a side-by-side-by-side arrangement.
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pubmed:grant | |
pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical |
http://linkedlifedata.com/resource/pubmed/chemical/1,6-hexamethylene diisocyanate,
http://linkedlifedata.com/resource/pubmed/chemical/1-(9-anthracenylmethyl)piperazine,
http://linkedlifedata.com/resource/pubmed/chemical/Air Pollutants, Occupational,
http://linkedlifedata.com/resource/pubmed/chemical/Anthracenes,
http://linkedlifedata.com/resource/pubmed/chemical/Cyanates,
http://linkedlifedata.com/resource/pubmed/chemical/Piperazines
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pubmed:status |
MEDLINE
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pubmed:month |
Oct
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pubmed:issn |
0002-8894
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:volume |
57
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
914-7
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pubmed:dateRevised |
2007-11-15
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pubmed:meshHeading |
pubmed-meshheading:8865600-Air Pollutants, Occupational,
pubmed-meshheading:8865600-Anthracenes,
pubmed-meshheading:8865600-Cyanates,
pubmed-meshheading:8865600-Environmental Monitoring,
pubmed-meshheading:8865600-Humans,
pubmed-meshheading:8865600-National Institute for Occupational Safety and Health (U.S.),
pubmed-meshheading:8865600-Paint,
pubmed-meshheading:8865600-Piperazines,
pubmed-meshheading:8865600-Reproducibility of Results,
pubmed-meshheading:8865600-Sensitivity and Specificity,
pubmed-meshheading:8865600-United States
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pubmed:year |
1996
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pubmed:articleTitle |
Evaluation of 1-(9-anthracenylmethyl) piperazine for the analysis of isocyanates in spray-painting operations.
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pubmed:affiliation |
Department of Chemistry, Southwest Texas State University, San Marcos 78666, USA.
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pubmed:publicationType |
Journal Article,
Comparative Study,
Research Support, U.S. Gov't, P.H.S.
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