Switch to
| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
7
|
| pubmed:dateCreated |
1981-11-22
|
| pubmed:abstractText |
A new fluorescent adduct has been isolated from the products of hydrolysis of DNA irradiated in the presence of 4,7-dimethylallopsoralen. The close similarity of the U.V. absorption spectrum of this compound to that of a synthetic 4',5'-dihydroallopsoralen shows that the 4',5'- double bond initially present in the 4,7-dimethylallopsoralen was saturated in the photoreaction with DNA, and this is consistent with a C4 cycloaddition at this level. The irradiation of the photoadduct at 254 nm provoked its photodissociation into the parent compounds, that is, thymine and 4,7-dimethylallopsoralen. These data are consistent with a cycloadduct between the 4',5'- double bond of 4,7-dimethnylallopsoralen and the 5,6- double bond of thymine.
|
| pubmed:language |
eng
|
| pubmed:journal | |
| pubmed:citationSubset |
IM
|
| pubmed:chemical | |
| pubmed:status |
MEDLINE
|
| pubmed:month |
Jul
|
| pubmed:issn |
0430-0920
|
| pubmed:author | |
| pubmed:issnType |
Print
|
| pubmed:volume |
36
|
| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
|
| pubmed:pagination |
606-13
|
| pubmed:dateRevised |
2009-6-5
|
| pubmed:meshHeading | |
| pubmed:year |
1981
|
| pubmed:articleTitle |
Photoreaction between 4,7-dimethylallopsoralen and DNA: isolation of a fluorescent cycloadduct between the furocoumarin and thymine.
|
| pubmed:publicationType |
Journal Article
|