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Predicate | Object |
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
2
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pubmed:dateCreated |
1979-9-17
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pubmed:abstractText |
A triacylglycerol analogue, rac-1,2-di-O-oleoyl-3-S-oleoyl-3-thioglycerol, was fed to rats and chyle acylglycerols were analyzed. Triacylglycerol was the dominating chyle lipid but X-triacyl-1-thioglycerol constituted approx. 6% of total chyle lipids. Its identity was verified by ultraviolet and mass spectra and its stereochemical structure by ORD and CD. The proportions of triacyl-1-thio-sn-glycerol/triacyl-3-thio-sn-glycerol were 63/37 and 78/22 in two experiments. Possible reasons for this stereospecificity are discussed. The study shows that the stereochemical configuration of lipids isolated from biological material can be assessed by ORD and CD.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical | |
pubmed:status |
MEDLINE
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pubmed:issn |
0009-3084
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:volume |
23
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
93-9
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pubmed:dateRevised |
2005-11-17
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pubmed:meshHeading |
pubmed-meshheading:455567-Animals,
pubmed-meshheading:455567-Chyle,
pubmed-meshheading:455567-Circular Dichroism,
pubmed-meshheading:455567-Intestinal Absorption,
pubmed-meshheading:455567-Lipid Metabolism,
pubmed-meshheading:455567-Male,
pubmed-meshheading:455567-Optical Rotatory Dispersion,
pubmed-meshheading:455567-Rats,
pubmed-meshheading:455567-Stereoisomerism,
pubmed-meshheading:455567-Triglycerides
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pubmed:articleTitle |
Digestion and absorption of trioleoyl-thioglycerol in the rat.
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pubmed:publicationType |
Journal Article
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