Linked Life Data

3722163

Source:http://linkedlifedata.com/resource/pubmed/id/3722163

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
19
pubmed:dateCreated
1986-8-6
pubmed:abstractText
In an attempt to verify the recent proposal that the heme d1 prosthetic group isolated from cytochrome cd1 is not a chlorin, but a dioxo-isobacteriochlorin (Chang, C. K. (1985) J. Biol. Chem. 260, 9520-9522), a model dioxo-isobacteriochlorin has been synthesized possessing a pi-electron system exactly identical to that as proposed. The presence of an acrylic acid substituent strongly perturbs the absorption spectrum of the chromophore and produces a visible spectrum virtually indistinguishable from that of the iron-free heme d1. Based on this finding, buttressed by additional spectral correspondence between the model iron heme and heme d1, we conclude that the proposed diketo ring structure is indeed correct, and the trivial names "dioneheme" and "acryloporphyrindione" are suggested for heme d1 and the demetallated macrocycle, respectively.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Jul
pubmed:issn
0021-9258
pubmed:author
pubmed:issnType
Print
pubmed:day
5
pubmed:volume
261
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
8593-6
pubmed:dateRevised
2006-11-15
pubmed:meshHeading
pubmed:year
1986
pubmed:articleTitle
The porphinedione structure of heme d1. Synthesis and spectral properties of model compounds of the prosthetic group of dissimilatory nitrite reductase.
pubmed:publicationType
Journal Article, Research Support, U.S. Gov't, P.H.S.