Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
3
pubmed:dateCreated
1988-8-2
pubmed:abstractText
The influence of solubilisation upon the reactivity of the nitroxyl BAPO with the free radicals produced in irradiated vesicle systems was investigated. The decomposition yield G(-BAPO) determined in didodecyldimethyl-ammonium bromide (DDAB) vesicle systems was found to be only 0.04, while in homogeneous aqueous solutions a value of 1.50 was observed. These results, as well as the EPR spectra of irradiated and nonirradiated samples, lead to the conclusion that BAPO is localized in the interior of the bilayer. This behavior is consistent with the hydrophobic character of the nitroxyl molecule due to its benzylidene group.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:issn
0250-7005
pubmed:author
pubmed:issnType
Print
pubmed:volume
8
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
507-9
pubmed:dateRevised
2005-11-17
pubmed:meshHeading
pubmed:articleTitle
Radiolysis of 4-benzylideneamino-2,2,6,6-tetramethylpiperidine-1-oxyl (BAPO) in aqueous didodecyldimethyl-ammonium bromide (DDAB) membrane mimetic systems.
pubmed:affiliation
Laboratory of Physical Chemistry, National Technical University, Campus of Zografou, Athens, Greece.
pubmed:publicationType
Journal Article