Switch to
Predicate | Object |
---|---|
rdf:type | |
lifeskim:mentions | |
pubmed:issue |
1
|
pubmed:dateCreated |
1990-9-11
|
pubmed:abstractText |
In the present study, we have optimized the use of a two nebulizer system for solid-surface room-temperature phosphorescence (SSRTP) as a selective, permanent record detector for high-performance liquid chromatography (HPLC). The chromatographic parameters and the analytical figures of merit of five well known phosphorescent compounds were compared to those obtained by ultraviolet detection. Calibration curves with satisfactory linear dynamic ranges and limits of detection in the nanogram and subnanogram level showed the feasibility of the SSRTP detector for HPLC. In addition, overlapped compounds were individually identified demonstrating that the selectivity of the proposed detector can be a useful feature in case of incomplete chromatographic separations of complex mixtures.
|
pubmed:grant | |
pubmed:language |
eng
|
pubmed:journal | |
pubmed:citationSubset |
IM
|
pubmed:chemical |
http://linkedlifedata.com/resource/pubmed/chemical/Benzopyrenes,
http://linkedlifedata.com/resource/pubmed/chemical/Carbazoles,
http://linkedlifedata.com/resource/pubmed/chemical/Fluorenes,
http://linkedlifedata.com/resource/pubmed/chemical/Phenanthrenes,
http://linkedlifedata.com/resource/pubmed/chemical/Pyrenes,
http://linkedlifedata.com/resource/pubmed/chemical/benzo(e)pyrene,
http://linkedlifedata.com/resource/pubmed/chemical/fluoranthene
|
pubmed:status |
MEDLINE
|
pubmed:month |
May
|
pubmed:issn |
0021-9673
|
pubmed:author | |
pubmed:issnType |
Print
|
pubmed:day |
25
|
pubmed:volume |
508
|
pubmed:owner |
NLM
|
pubmed:authorsComplete |
Y
|
pubmed:pagination |
37-49
|
pubmed:dateRevised |
2007-11-14
|
pubmed:meshHeading |
pubmed-meshheading:2380318-Benzopyrenes,
pubmed-meshheading:2380318-Carbazoles,
pubmed-meshheading:2380318-Chromatography, High Pressure Liquid,
pubmed-meshheading:2380318-Fluorenes,
pubmed-meshheading:2380318-Luminescent Measurements,
pubmed-meshheading:2380318-Phenanthrenes,
pubmed-meshheading:2380318-Pyrenes,
pubmed-meshheading:2380318-Temperature,
pubmed-meshheading:2380318-Ultraviolet Rays
|
pubmed:year |
1990
|
pubmed:articleTitle |
Solid-surface room-temperature phosphorescence detection for high-performance liquid chromatography.
|
pubmed:affiliation |
Department of Chemistry, University of Florida, Gainesville 32611.
|
pubmed:publicationType |
Journal Article,
Comparative Study,
Research Support, U.S. Gov't, P.H.S.,
Research Support, Non-U.S. Gov't
|