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pubmed-article:2224903pubmed:abstractTextThe yields of disaccharide glycosylation products in tetramethylammonium bromide or silver triflate-collidine activated reactions between hindered alcohols and glycosyl halides were not greatly ++affected when a pressure of 15 kbar was applied. The formation of orthoester products was greatly increased under pressure. When orthoester formation was not possible both disaccharides and the related N-glycosyl collidinium salts were found.lld:pubmed
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pubmed-article:2224903pubmed:articleTitleHigh-pressure glycosylations of unreactive alcohols and the formation of N-glycosyl collidinium salts.lld:pubmed
pubmed-article:2224903pubmed:affiliationDepartment of Chemistry, University of California, Berkeley 94720.lld:pubmed
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