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rdf:type |
|
|
lifeskim:mentions |
|
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pubmed:issue |
1
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pubmed:dateCreated |
1990-12-19
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pubmed:abstractText |
The yields of disaccharide glycosylation products in tetramethylammonium bromide or silver triflate-collidine activated reactions between hindered alcohols and glycosyl halides were not greatly ++affected when a pressure of 15 kbar was applied. The formation of orthoester products was greatly increased under pressure. When orthoester formation was not possible both disaccharides and the related N-glycosyl collidinium salts were found.
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pubmed:language |
eng
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pubmed:journal |
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pubmed:citationSubset |
IM
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pubmed:chemical |
|
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pubmed:status |
MEDLINE
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pubmed:month |
Aug
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pubmed:issn |
0008-6215
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pubmed:author |
|
|
pubmed:issnType |
Print
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|
pubmed:day |
1
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pubmed:volume |
203
|
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pubmed:owner |
NLM
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|
pubmed:authorsComplete |
Y
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pubmed:pagination |
47-56
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pubmed:dateRevised |
2006-11-15
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pubmed:meshHeading |
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pubmed:year |
1990
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pubmed:articleTitle |
High-pressure glycosylations of unreactive alcohols and the formation of N-glycosyl collidinium salts.
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pubmed:affiliation |
Department of Chemistry, University of California, Berkeley 94720.
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pubmed:publicationType |
Journal Article,
Research Support, U.S. Gov't, Non-P.H.S.
|
