Source:http://linkedlifedata.com/resource/pubmed/id/21836873
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| Predicate | Object |
|---|---|
| rdf:type | |
| pubmed:issue |
Pt 7
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| pubmed:dateCreated |
2011-8-12
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| pubmed:abstractText |
The asymmetric unit of title compound, [Cd(C(9)H(6)NO(2))(2)(C(10)H(8)N(2))(2)]·0.5C(10)H(8)N(2)·2H(2)O, consists of one complex mol-ecule, one half of an uncoordinated 2,2'-bipyridine mol-ecule and two solvent water mol-ecules. The uncoordinated 2,2'-bipyridine mol-ecule is located on a center of symmetry. Within the complex mol-ecule, the Cd(II) atom is coordinated by four N atoms from two 2,2'-bipyridine ligands and three O atoms from two 1H-indole-2-carboxyl-ate anion ligands, completing a distorted CdN(4)O(3) penta-gonal bipyra-mid. The mol-ecules are assembled into one-dimensional chains along the [100] direction through classical hydrogen bonds (O-H?N, N-H?O and O-H?O). The resulting chains are further connected into two-dimensional supra-molecular layers parallel to the (110) direction by inter-molecular classical hydrogen bonds (N-H?O and O-H?O) from adjacent chains. A three-dimensional supra-molecular network is formed via interlayer and O-H?O hydrogen bonds.
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| pubmed:commentsCorrections | |
| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Jul
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| pubmed:issn |
1600-5368
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| pubmed:author | |
| pubmed:issnType |
Electronic
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| pubmed:day |
1
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| pubmed:volume |
67
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
m879-80
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| pubmed:year |
2011
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| pubmed:articleTitle |
Bis(2,2'-bipyridine-?N,N')bis-(1H-indole-2-carboxyl-ato-?O,O')cadmium-2,2'-bipyridine-water (1/0.5/2).
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| pubmed:affiliation |
College of Pharmaceutics and Material Engineering, Jinhua College of Profession and Technology, Jinhua, Zhejiang 321007, People's Republic of China.
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| pubmed:publicationType |
Journal Article
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