Source:http://linkedlifedata.com/resource/pubmed/id/21836847
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
Pt 7
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pubmed:dateCreated |
2011-8-12
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pubmed:abstractText |
In the title compound, {[Mn(6)(C(8)H(4)O(4))(6)(C(4)H(9)NO)(8)]·H(2)O}(n), two of the Mn atoms are six-coordinated by six O atoms from three benzene-1,4-dicarboxyl-ate (bdc) ligands and two trans DMA (dimethyl-acetamide) mol-ecules, whereas two other Mn atoms, located on inversion centers, are both in octa-hedral coordinations by six bdc O atoms. The discrete trinuclear manganese secondary building units (SBU) of Mn(3)(O(2)CR)(6) ({-Mn-Mn-Mn-}) are linked through bdc ligands, forming a chain, while the discrete trinuclear SBU of {-Mn-Mn-Mn-} are bridged, forming another chain]. The two types of chains are linked through bdc ligands, resulting in the formation of a layer with 3(6) topology. Weak O-H?O and O-H?N hydrogen-bonding inter-actions involving the disordered water molecule (half-occupation) extend the two-dimensional layers into a three-dimensional supra-molecular framework.
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pubmed:commentsCorrections |
http://linkedlifedata.com/resource/pubmed/commentcorrection/21836847-16261238,
http://linkedlifedata.com/resource/pubmed/commentcorrection/21836847-16983162,
http://linkedlifedata.com/resource/pubmed/commentcorrection/21836847-18156677,
http://linkedlifedata.com/resource/pubmed/commentcorrection/21836847-19384449
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pubmed:language |
eng
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pubmed:journal | |
pubmed:status |
PubMed-not-MEDLINE
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pubmed:month |
Jul
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pubmed:issn |
1600-5368
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pubmed:author | |
pubmed:issnType |
Electronic
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pubmed:day |
1
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pubmed:volume |
67
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
m843-4
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pubmed:year |
2011
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pubmed:articleTitle |
Poly[[hexa-kis-(?-benzene-1,4-dicarboxyl-ato)octa-kis-(N,N-dimethyl-acetamide)-hexa-manganese(II)] monohydrate].
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pubmed:publicationType |
Journal Article
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